As a celebrated socialite in London high society, Mrs. Livingstone fully utilized her appearances and status. She not only became the first foreign patron of Almack's Club since its establishment in 1765 but also, as a German-Russian, faithfully incorporated the German waltz into the club's dance options.
When her husband was in London, Mrs. Livingstone excelled in fulfilling her duties as a devoted wife and mother, but when the Earl went out, she occasionally spiced up her mundane life with visits from the Austrian Prime Minister Metternich and Viscount Palmeston, who were on business in London.
By maintaining close relationships with these prominent European politicians, she acquired a great deal of 'unexpected intelligence' for Russia. Within the Russian court, she was considered at least as important politically as her ambassador husband, and sometimes even more so.